Niobium chloride NbCl5 CAS 10026-12-7
Synonyms: NbCl5;Niobium chloride (NbCl5);niobiumchloride(nbcl5);COLUMBIUM CHLORIDE;COLUMBIUM PENTACHLORIDE;NIOBIUM PENTACHLORIDE;NIOBIUM(V) CHLORIDE;NIOBIUM(+5)CHLORIDE
CAS: 10026-12-7
MF: Cl5Nb
MW: 270.17
EINECS: 233-059-8
Melting point 204.7 °C(lit.)
Boiling point 254 °C(lit.)
density 2.75 g/mL at 25 °C(lit.)
vapor pressure 22.8hPa at 153.8℃
Fp 248.2°C
storage temp. no restrictions.
solubility Soluble in alcohol, hydrochloric acid, carbon tetrachloride and chloroform.
form powder
color Yellow
Niobium chloride NbCl5 CAS 10026-12-7
Niobium chloride NbCl5 CAS 10026-12-7
Used to form mixed chloro-aryloxide compounds, such as [Nb(OC6H3-2,6-i-Pr2)2Cl3]2, which form pyridine or phosphine adducts with a distorted six-coordinate geometry.
Used as Lewis acid catalyst in organic synthesis.
Niobium(V) chloride is the precursor in the preparation of pure niobium, and ferroniobium. It is used as a Lewis acid catalyst in organic synthesis in activating alkenes in the carbonyl-ene reaction and the Diels-Alder reaction.
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